Aircraft-based observation of gaseous pollutants in the lower troposphere over the Beijing-Tianjin-Hebei region

Highlights: • Aircraft-based measurements were conducted over the Beijing-Tianjin-Hebei region. • First simultaneous observations of tethered balloon and aircraft were analyzed. • Planetary boundary layer significantly suppressed the vertical exchange. • Southerly air masses resulted in the high concentrations of gaseous pollutants. To investigate the spatial and vertical distribution of atmospheric pollutants (SO₂, NO_x, CO and O₃), aircraft-based measurements (model: Yun-12, 12 flights, 27 h total flight time) were conducted from near the surface up to 2400 m over the Beijing-Tianjin-Hebei (BTH) region between June 17th and July 22nd 2016. The results showed that high concentrations of primary gaseous pollutants (SO₂, NO_x, CO) were generally present in Beijing, Tianjin, Langfang and Tangshan areas, while high values of O₃ frequently appeared in areas far from the city. The flights at noon and dusk measured higher O₃ concentrations at 600 m and lower O₃ concentrations at higher altitudes, implying a strong influence by photochemical production. Back trajectory analysis suggested that the high levels of gaseous pollutants, especially at 600 m, were associated with pollution sources transported from the southerly direction during the observation period. The first simultaneous vertical distribution measurements using aircraft and tethered balloon were conducted in Gaocun (a rural site between Beijing and Tianjin) on June 17th. The results indicated that an inversion layer at the top of the planetary boundary layer (PBL) significantly suppressed vertical exchange through the PBL and resulted in a "two-layer" vertical distribution of pollutants above and below the PBL. Additionally, a residual high O₃ layer (79.9 ± 2.5 ppb, 500–1000 m) was observed above the PBL, and it contributed to the surface peak O₃ level at noon through downward transport along with the opening up of the PBL. These results indicate that coupled effects of horizontal and vertical transport should be investigated in future studies to improve the chemical transport models used to study the vertical distribution and regional transport over the BTH region.