Photocatalytic degradation of indole in a circulating upflow reactor by UV/TiO2 process-Influence of some operating parameters
- 1. Laboratoire d'hydraulique appliquee et environnement, Universite A. Mira, 06000 Bejaia (Algeria)
- 2. Universite Europeenne de Bretagne (France)
- 3. Laboratoire Chimie et Ingenierie des Procedes, UMR 6226, Sciences Chimiques de Rennes, Ecole Nationale Superieure de Chimie de Rennes, 35700 Rennes (France)
Description
The present work involves the photocatalytic degradation of indole on a recirculating reactor. The effects of various factors as initial concentration of indole, catalyst-loading, pH, agitation and flow rate of the solution on the photodegradation were examined. The experimental results indicate that the optimal pH for indole elimination is about 6-7; the effect of catalyst loading shows an optimal value (1 g/L) which is necessary to degrade indole; the increase of recirculating rate leads to a decrease of degradation rate due to the reduction of the residence time; the agitation speed has a slight influence on the indole degradation by improving the mass transfer step. Finally, L-H model was used to fit experimental results concerning the influence of experimental data. L-H model constants' were determined also.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jhazmat.2008.12.047Additional details
Identifiers
- DOI
- 10.1016/j.jhazmat.2008.12.047;
- PII
- S0304-3894(08)01869-4;
Publishing Information
- Journal Title
- Journal of Hazardous Materials
- Journal Volume
- 166
- Journal Issue
- 2-3
- Journal Page Range
- p. 1244-1249
- ISSN
- 0304-3894
- CODEN
- JHMAD9
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 43121592
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CATALYSTS; INDOLES; MASS TRANSFER; PHOTOCATALYSIS; TITANIUM OXIDES; WASTE WATER
- Descriptors DEC
- AROMATICS; AZAARENES; AZOLES; CATALYSIS; CHALCOGENIDES; HETEROCYCLIC COMPOUNDS; HYDROGEN COMPOUNDS; LIQUID WASTES; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PYRROLES; TITANIUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; WASTES; WATER
Optional Information
- Copyright
- Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.