Published February 1979
| Version v1
Journal article
A synthetic study of the solid solutions in the systems La2(CO3)3.8H2O-Ce2(CO3)3.8H2O and La(OH)CO3-Ce(OH)CO3
Description
The solid solutions in the systems La2(CO3)3.8H2O-Ce2(CO3)3.8H2O and La(OH)CO3-Ce(OH)CO3 have been synthesized by the hydrolysis of the lanthanum-cerium trichloroacetates. The X-ray diffraction data of the soild solutions of La2(CO3)3.8H2O-Ce2(CO3)3.8H2O indicated a lanthanite-type structure while the data of La(OH)CO3-Ce(OH)CO3 indicated a bastnaesite-type structure. The correlations between lanthanite, bastnaesite, and calkinsite, and the lanthanite-bastnaesite transformation are discussed. (author)
Additional details
Publishing Information
- Journal Title
- Bull. Chem. Soc. Jpn.
- Journal Volume
- 52
- Journal Issue
- 2
- Series
- Bull. Chem. Soc. Jpn.
- Journal Page Range
- 428-432
- ISSN
- 0009-2673
INIS
- Country of Publication
- Japan
- Country of Input or Organization
- Japan
- INIS RN
- 11540522
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- CERIUM CARBONATES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CRYSTAL STRUCTURE; ELECTRON MICROPROBE ANALYSIS; EXPERIMENTAL DATA; GRAPHS; HYDRATES; HYDROLYSIS; INFRARED SPECTRA; LANTHANUM CARBONATES; MONOCARBOXYLIC ACIDS; ORGANIC CHLORINE COMPOUNDS; SOLID SOLUTIONS; TABLES; THERMAL ANALYSIS; X-RAY DIFFRACTION
- Descriptors DEC
- CARBON COMPOUNDS; CARBONATES; CARBOXYLIC ACIDS; CERIUM COMPOUNDS; CHEMICAL ANALYSIS; CHEMICAL REACTIONS; COHERENT SCATTERING; DATA; DATA FORMS; DECOMPOSITION; DIFFRACTION; DISPERSIONS; HOMOGENEOUS MIXTURES; INFORMATION; LANTHANUM COMPOUNDS; MIXTURES; NONDESTRUCTIVE ANALYSIS; NUMERICAL DATA; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; OXYGEN COMPOUNDS; RARE EARTH COMPOUNDS; SCATTERING; SOLUTIONS; SOLVOLYSIS; SPECTRA; SYNTHESIS