Published August 1998
| Version v1
Journal article
On bistability in molecular systems: Photomagnetic studies of inorganic complexes
Description
Photo-induced effects have been detected by magnetic measurements, Moessbauer spectroscopy and reflectivity. The LIESST effect has been achieved in the spin-crossover system [FexCo1-x(btr)2(NCS)2].H2O. We investigated the purely photo-induced magnetism of a Prussian Blue analogue Rb0.52Co[Fe(CN)6]0.84, 2.31 H2O, involving an optical electron transfer from FeII to CoIII. Inherent aspects of photomagnetic experiments are described: bulk and surface effects, magnetic and electronic metastabilities of the photo-excited state
Additional details
Identifiers
Publishing Information
- Journal Title
- Hyperfine Interactions
- Journal Volume
- 113
- Journal Issue
- 1-4
- Journal Page Range
- p. 37-46
- ISSN
- 0304-3843
- CODEN
- HYINDN
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 40058549
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- CARBON NITRIDES; CYANIDES; ELECTRON TRANSFER; EXCITED STATES; FERROCYANIDES; MAGNETISM; MOESSBAUER EFFECT; POTASSIUM COMPOUNDS; REFLECTIVITY; SPIN; SURFACES; WATER
- Descriptors DEC
- ALKALI METAL COMPOUNDS; ANGULAR MOMENTUM; CARBON COMPOUNDS; COMPLEXES; ENERGY LEVELS; HYDROGEN COMPOUNDS; IRON COMPLEXES; NITRIDES; NITROGEN COMPOUNDS; OPTICAL PROPERTIES; OXYGEN COMPOUNDS; PARTICLE PROPERTIES; PHYSICAL PROPERTIES; PNICTIDES; SURFACE PROPERTIES; TRANSITION ELEMENT COMPLEXES
Optional Information
- Copyright
- Copyright (c) 1998 Kluwer Academic Publishers