Trace organics in AGR coolants

Several analytical techniques have been employed in previous studies of the stable organic compounds arising from the radiolysis of methane/carbon monoxide/carbon dioxide coolants. The majority of this early information was collected from the Windscale AGR prototype. Analyses were also carried out on the liquors obtained from the WAGR humidryers. Three classes of compound were found in the liquors; aliphatic acids in the aqueous phase and methyl ketones and aromatic hydrocarbons in the oily phase. Acetic acid was found to be the predominant carboxylic acid. This paper outlines the major findings from a recent analytical survey of coolants taken over a wide range of dose rate, pressure, temperature and composition, from materials testing reactor facilities, WAGR and CAGR. (author)