Published September 1, 1990
| Version v1
Journal article
Comment on ''Valence-band states in Bi2(Ca,Sr,La)3Cu2O8''
Creators
- 1. Department of Materials Science, Massachusetts Institute of Technology, Cambridge, MA (USA)
Description
In a recent paper, Wells et al. conclude from angle-resolved photoemission spectroscopy that the electronic states at the Fermi energy (EF) of Bi2(Ca,Sr,La)3Cu2O8 have mainly O 2px and 2py symmetry, while O 2pz-like states are not permitted by symmetry at EF. I point out here a deficiency in Wells' et al. symmetry analysis which, when corrected, allows for a significant O 2pz contribution at EF. The resultant degenerate O pz--O pz ''resonant π bonds'' at EF parallel to the Cu-O a-b planes, promoted by significant Cu dxz,yz--O pz π*-antibonding hybridization, along with their associated shallow ''double-well'' potentials, are the basis for a dynamic Jahn-Teller mechanism of high-Tc superconductivity in cuprates
Additional details
Publishing Information
- Journal Title
- Physical Review, B: Condensed Matter
- Journal Volume
- 42
- Journal Issue
- 7
- Series
- Phys. Rev., B: Condens. Matter.
- Journal Page Range
- 4783-4784
- ISSN
- 0163-1829
- CODEN
- PRBMD
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 22015535
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- BAND THEORY; BISMUTH OXIDES; CALCIUM OXIDES; COPPER OXIDES; ENERGY-LEVEL DENSITY; FERMI LEVEL; HIGH-TC SUPERCONDUCTORS; HYBRIDIZATION; JAHN-TELLER EFFECT; LANTHANUM OXIDES; PHOTOEMISSION; STRONTIUM OXIDES
- Descriptors DEC
- ALKALINE EARTH METAL COMPOUNDS; BISMUTH COMPOUNDS; CALCIUM COMPOUNDS; CHALCOGENIDES; COPPER COMPOUNDS; EMISSION; ENERGY LEVELS; LANTHANUM COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; RARE EARTH COMPOUNDS; SECONDARY EMISSION; STRONTIUM COMPOUNDS; SUPERCONDUCTORS; TRANSITION ELEMENT COMPOUNDS