Published July 2019 | Version v1
Journal article

Effect of the Film Thickness on the Work Function of Pt-Ru Bimetallic Alloy Films by Atomic Layer Deposition

  • 1. Pusan National University, Busan (Korea, Republic of)

Description

The work function (WF) of Pt-Ru bimetallic alloy (BA) films prepared by atomic layer deposition (ALD) was systemically investigated depending on the thickness. Pt-Ru BA films were deposited using a supercycle consisted of 10 subcycles for Pt and 1 subcycle for Ru. And, the thicknesses of Pt-Ru BA films were carefully controlled from 2.9 to 35.7 nm through changing the number of supercycles. Although a fixed ALD supercycle was used, the composition of Pt-Ru BA films was gradually changed and then saturated to Pt: ∼92 at.% and Ru: ∼8 at.% with increasing the film thickness. In addition, the microstructural evolution of Pt-Ru BA films happened from island-like nuclei to continuous film at an initial growth stage. As a result, the WF and electrical resistivity of ALD Pt-Ru BA films exhibited saturated values of ∼5.36 eV and ∼19.95 μΩ·cm, respectively at higher than 8.7 nm thickness.

Additional details

Publishing Information

Journal Title
Journal of the Korean Physical Society
Journal Volume
75
Journal Issue
1
Series
12 refs, 3 figs
Journal Page Range
p. 1-4
ISSN
0374-4884

INIS

Country of Publication
Korea, Republic of
Country of Input or Organization
Korea, Republic of
INIS RN
50066805
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Descriptors DEI
CONTROL; EVOLUTION; FILMS; PLATINUM ALLOYS; THICKNESS; WORK FUNCTIONS
Descriptors DEC
ALLOYS; DIMENSIONS; FUNCTIONS; PLATINUM METAL ALLOYS; TRANSITION ELEMENT ALLOYS