Published December 2, 2005 | Version v1
Journal article

Competition between Order and Phase Separation in Au-Ni

  • 1. Max-Planck-Institut fuer Metallforschung, Heisenbergstrasse 3, D-70569 Stuttgart (Germany)
  • 2. Universitaet Stuttgart, Institut fuer Theoretische und Angewandte Physik, D-70569 Stuttgart (Germany)
  • 3. Northwestern University, Evanston, Illinois 60208 (United States)
  • 4. Department of Materials, University of Oxford, Oxford OX1 3PH (United Kingdom)
  • 5. European Synchrotron Radiation Facility, F-38043 Grenoble (France)

Description

We have measured and theoretically analyzed the diffuse scattering in the binary alloy system Au-Ni, which has been proposed as a testing ground for theories of alloy phase stability. We found strong evidence that in the alloys Au3Ni and Au3Ni2, fluctuations of both ordering- and clustering-type are competing with each other. Our results resolve a long-standing controversy on the balance of relaxation and mixing energies in this alloy system and explain recent findings of ordering in thin Au-Ni films

Additional details

Publishing Information

Journal Title
Physical Review Letters
Journal Volume
95
Journal Issue
23
Journal Page Range
p. 235703-235703.4
ISSN
0031-9007
CODEN
PRLTAO

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
37015661
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
BINARY ALLOY SYSTEMS; DIFFUSE SCATTERING; GOLD ALLOYS; NICKEL ALLOYS; ORDER-DISORDER TRANSFORMATIONS; PHASE STABILITY; X-RAY DIFFRACTION
Descriptors DEC
ALLOY SYSTEMS; ALLOYS; COHERENT SCATTERING; DIFFRACTION; PHASE TRANSFORMATIONS; SCATTERING; STABILITY; TRANSITION ELEMENT ALLOYS

Optional Information

Notes
(c) 2005 The American Physical Society