Published January 1, 2017 | Version v1
Journal article Metadata-only

XPS and NMR analysis on 12CaO·7Al2O3

Creators

  • 1. School of Materials Science and Engineering, Hubei University, Wuhan 430062 (China)
  • 2. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070 (China)

Description

12CaO·7Al2O3 (C12A7) glass was prepared by the melt quenching method. The glass transition temperature ( T g) and the crystallization temperature ( T c) of C12A7 glass are about 1050 K and 1194 K, respectively, measured by the differential scanning calorimetry (DSC). The structure of C12A7 glass was investigated by X-ray photoelectron spectroscopy (XPS) as well as magic angle spinning-nuclear magnetic resonance spectroscopy (MAS-NMR). Analysis shows that Al coordination number is about four in C12A7 glass, in which AlO4 tetrahedrons and bridging oxygens (BO) constitute the glass network. Ca2+ produces a few of non-bridging oxygens (NBO), which become neighbours of Al. (paper)

Availability note (English)

Available from http://dx.doi.org/10.1088/1757-899X/167/1/012017

Additional details

Identifiers

DOI
10.1088/1757-899X/167/1/012017;

Publishing Information

Journal Title
IOP Conference Series. Materials Science and Engineering (Online)
Journal Volume
167
Journal Issue
1
Journal Page Range
[5 p.]
ISSN
1757-899X

Conference

Title
1. international conference on new material and chemical industry
Acronym
NMCI2016
Dates
19-21 Nov 2016
Place
Sanya (China)

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
49077912
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ALUMINIUM OXIDES; CALCIUM IONS; CALCIUM OXIDES; CALORIMETRY; COMPLEXES; COORDINATION NUMBER; CRYSTALLIZATION; GLASS; NUCLEAR MAGNETIC RESONANCE; OXYGEN; TEMPERATURE RANGE 1000-4000 K; TRANSITION TEMPERATURE; X-RAY PHOTOELECTRON SPECTROSCOPY
Descriptors DEC
ALKALINE EARTH METAL COMPOUNDS; ALUMINIUM COMPOUNDS; CALCIUM COMPOUNDS; CHALCOGENIDES; CHARGED PARTICLES; ELECTRON SPECTROSCOPY; ELEMENTS; IONS; MAGNETIC RESONANCE; NONMETALS; OXIDES; OXYGEN COMPOUNDS; PHASE TRANSFORMATIONS; PHOTOELECTRON SPECTROSCOPY; PHYSICAL PROPERTIES; RESONANCE; SPECTROSCOPY; TEMPERATURE RANGE; THERMODYNAMIC PROPERTIES