Published October 1991 | Version v1
Journal article

Structural investigations of K3-x[InX6-x(H2O)x,nH2O]. I. Crystallographic characterization (X=Br); comparison of indium-ligand distances

  • 1. Lille-1 Univ., 59 - Villeneuve-d'Ascq (France)
  • 2. Ecole nationale superieure de chimie de Lille, 59 - Villeneuve-d'Ascq (France)

Description

We present different compounds existing in the potassium bromoindates family, where the CN of the central atom vary from six to four. The crystal structures have been refined from their isomorphous chlorinated homologues. We propose a comparison of In-Br bond lengths as a function of the central atom CN and of the substitutional degree of halide ligands by water molecule

Abstract (French)

Nous presentons les differents composes rencontres dans la famille des bromoindates de potassium, ou la coordinence de l'atome central passe de six a quatre. Nous resumons dans cette etude, les caracteristiques cristallographiques dont les structures ont ete affinees par isotypie avec leurs homologues chlores. Nous proposons une comparaison des longueurs des liaisons In-Br en fonction de la coordinence de l'atome central d'une part, et en fonction du degre de substitution des ligands halogenes par des ligands neutres H2O d'autre part

Additional details

Additional titles

Original title (French)
Investigations structurales des composes K

Publishing Information

Journal Title
Journal de Chimie Physique et de Physico-Chimie Biologique
Journal Volume
88
Journal Issue
10
Series
J. Chim. Phys. Phys.-Chim. Biol.
Journal Page Range
2041-2055
ISSN
0021-7689
CODEN
JCPBA

Conference

Title
1. Seminar on Physical Chemistry of solid materials.
Original Conference Title
REMCES-4: 1. Seminaire Francophone sur la Physico-Chimie des materiaux solides
Acronym
REMCES-4
Dates
1-4 Nov 1989.
Place
Fes (Morocco).

INIS

Country of Publication
France
Country of Input or Organization
France
INIS RN
23052365
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
BOND LENGTHS; COMPLEXES; COORDINATION NUMBER; CRYSTAL STRUCTURE; INDIUM BROMIDES; LIGANDS; POTASSIUM BROMIDES
Descriptors DEC
ALKALI METAL COMPOUNDS; BROMIDES; BROMINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; INDIUM COMPOUNDS; POTASSIUM COMPOUNDS