Stable isotope geochemistry : definitions, terminology, measurement and some applications

In 1936, Alfred Nier produced the first precise measurement of isotope abundance ratios and his design still remains the basis of stable isotope mass spectrometry. With this gift from the physicists for routine measurement of isotope ratios, earth scientists began to explore the natural variations of isotopes. Thus began a new era in geoscience research with the hydrological cycle and marine palaeoclimatic research being the first topics to be investigated. Stable isotope measurements have been applied to many fundamental problems in geochemistry, petrology, and paleoclimatology, as well as related fields in archaeology, anthropology, physical chemistry, biology and forensic sciences. These applications can be broadly classified into four main types: 1. Thermometry: Formation temperatures of rock and mineral systems are determined on the basis of temperature-dependent fractionations of the isotopic ratios between two or more cogenetic phases. 2. Tracers: Reservoirs like the ocean, the mantle, meteoric waters and organic matter have distinct stable isotope signatures that can be used to trace the origin of rocks, fluids, contaminants etc. 3. Reaction mechanism: Distinctions can be made between diffusion and recrystallization, open and closed systems and bacterial and thermogenic processes. 4. Chemostratigraphy: Abrupt changes (excursions) in the stable isotope ratios of ocean sediments and certain terrestrial materials can be used as stratigraphic markers. (author). 91 refs., 12 figs., 2 tabs.