Reply to ''Comment on 'Relation between copper L x-ray fluorescence and 2p x-ray photoelectron spectroscopies' ''
Creators
- 1. Department of Materials Science and Engineering, Kyoto University, Sakyo-ku, Kyoto 606-01 (Japan)
- 2. The Institute of Physical and Chemical Research (RIKEN), 2-1 Hirosawa, Wako, Saitama 351-01 (Japan)
- 3. Department of Applied Chemistry, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113 (Japan)
Description
Ohno's preceding Comment [Phys. Rev. B 52, 6127 (1995)] was based on experimental raw spectra of copper L x-ray emission. The Cu L x-ray emission spectra were, however, heavily smeared by the self-absorption effect, which was a source of contradiction. The electronic structure of divalent copper oxide was calculated placing one core hole and two 3d holes, with the result that the spectator 3d holes were delocalized in the adiabatic limit. This implies that the spectator 3d hole produced by the L1,2L3M4,5 Coster-Kronig transition preceding the L3-M x-ray emission will be mostly delocalized at the time of the L3-M x-ray emission, and thus the spectator satellite will be weaker than is expected for the free atom. Ohno did not consider this delocalization, which was another source of contradiction
Additional details
Publishing Information
- Journal Title
- Physical Review. B, Condensed Matter
- Journal Volume
- 52
- Journal Issue
- 8
- Journal Page Range
- p. 6129-6131.
- ISSN
- 0163-1829
- CODEN
- PRBMDO
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 27021236
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- COPPER; ELECTRONIC STRUCTURE; ENERGY-LEVEL TRANSITIONS; FLUORESCENCE; HARTREE-FOCK METHOD; HIGH-TC SUPERCONDUCTORS; PHOTOELECTRON SPECTROSCOPY; VARIATIONAL METHODS
- Descriptors DEC
- CALCULATION METHODS; ELECTRON SPECTROSCOPY; ELEMENTS; EMISSION; LUMINESCENCE; METALS; PHOTON EMISSION; SPECTROSCOPY; SUPERCONDUCTORS; TRANSITION ELEMENTS