Published 2021
| Version v1
Journal article
Nickel-catalyzed electro-carboxylation of allylic halides with CO2
- 1. AnHui Province Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246011, (China)
- 2. School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, (China)
Description
Nickel-catalyzed regioselective electro-carboxylation of allylic halides with CO2 at atmospheric pressure has been developed by adjusting reaction parameters, including catalyst, solvent, temperature and additive. β,γ-Unsaturated carboxylic acids were obtained in moderate to good yields and with high chain selectivity. This reaction shows tolerance to functional groups. In addition, cyclic voltammetry was performed to provide the possible mechanism of nickel-catalyzed CO2 allylation. (authors)
Availability note (English)
Available from doi: http://dx.doi.org/10.1039/D1NJ02006DAdditional details
Identifiers
- DOI
- 10.1039/D1NJ02006D;
Publishing Information
- Journal Title
- New Journal of Chemistry
- Journal Volume
- 45
- Journal Issue
- no.29
- Journal Page Range
- p. 13137-13141
- ISSN
- 1144-0546
INIS
- Country of Publication
- France
- Country of Input or Organization
- France
- INIS RN
- 53012740
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S54: ENVIRONMENTAL SCIENCES;
- Descriptors DEI
- CARBON DIOXIDE; CARBOXYLATION; CATALYSTS; HALIDES; NICKEL; SOLVENTS; VOLTAMETRY
- Descriptors DEC
- CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHEMICAL REACTIONS; ELEMENTS; HALOGEN COMPOUNDS; METALS; OXIDES; OXYGEN COMPOUNDS; TRANSITION ELEMENTS