Published October 2016
| Version v1
Journal article
Bounded energy exchange as an alternative to the third law of thermodynamics
Creators
Description
This paper introduces a postulate explicitly forbidding the extraction of an infinite amount of energy from a thermodynamic system. It also introduces the assumption that no measuring equipment is capable of detecting arbitrarily small energy exchanges. The Kelvin formulation of the second law is reinterpreted accordingly. Then statements related to both the unattainability version and the entropic version of the third law are derived. The value of any common thermodynamic potential of a one-component system at absolute zero of temperature is ascertained if some assumptions with regard to the state space can be made. The point of view is the phenomenological, macroscopic and non-statistical one of classical thermodynamics.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.aop.2016.07.031Additional details
Identifiers
- DOI
- 10.1016/j.aop.2016.07.031;
- PII
- S0003-4916(16)30132-4;
Publishing Information
- Journal Title
- Annals of Physics (New York)
- Journal Volume
- 373
- Journal Page Range
- p. 665-681
- ISSN
- 0003-4916
- CODEN
- APNYA6
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 48064346
- Subject category
- S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
- Descriptors DEI
- ENERGY TRANSFER; ENTHALPY; ENTROPY; THERMODYNAMICS
- Descriptors DEC
- PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES
Optional Information
- Copyright
- Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.