Published October 2016 | Version v1
Journal article

Bounded energy exchange as an alternative to the third law of thermodynamics

Description

This paper introduces a postulate explicitly forbidding the extraction of an infinite amount of energy from a thermodynamic system. It also introduces the assumption that no measuring equipment is capable of detecting arbitrarily small energy exchanges. The Kelvin formulation of the second law is reinterpreted accordingly. Then statements related to both the unattainability version and the entropic version of the third law are derived. The value of any common thermodynamic potential of a one-component system at absolute zero of temperature is ascertained if some assumptions with regard to the state space can be made. The point of view is the phenomenological, macroscopic and non-statistical one of classical thermodynamics.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.aop.2016.07.031

Additional details

Identifiers

DOI
10.1016/j.aop.2016.07.031;
PII
S0003-4916(16)30132-4;

Publishing Information

Journal Title
Annals of Physics (New York)
Journal Volume
373
Journal Page Range
p. 665-681
ISSN
0003-4916
CODEN
APNYA6

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
48064346
Subject category
S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
Descriptors DEI
ENERGY TRANSFER; ENTHALPY; ENTROPY; THERMODYNAMICS
Descriptors DEC
PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES

Optional Information

Copyright
Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.