Published March 2010 | Version v1
Journal article

Structural analysis of skutterudite compound by single crystal neutron diffraction

Creators

  • 1. Japan Atomic Energy Agency, Advanced Science Research Center, Tokai, Ibaraki (Japan)

Description

Structural analysis on the cubic skutterudite compound PrOs4Sb12 by single crystal neutron diffraction is presented. There are surge of interests on large-amplitude thermal vibration of a guest ion inside an over-sized cage, called 'rattling', and its relationship with their physical properties. A combination of single crystal neutron diffraction and analysis by maximum-entropy method offers an ability to reveal detailed potential shape and anharmonicity in real space without the need for specific model. A clear picture of rattling in PrOs4Sb12 is successfully revealed. (author)

Availability note (English)

Available from http://dx.doi.org/10.3769/radioisotopes.59.249

Additional details

Identifiers

Publishing Information

Journal Title
Radioisotopes (Tokyo)
Journal Volume
59
Journal Issue
3
Journal Page Range
p. 249-256
ISSN
0033-8303

Optional Information

Notes
22 refs., 5 figs.