Speed of sound measurements of liquid C1–C4 alkanols

Highlights: • Speeds of sound in alkanols were measured in a wide temperature and pressure range. • A pulse-echo method with a double path type sensor was employed. • A double polynomial equation was used to fit the experimental speed of sound data. • The accurate results were compared with available literature sources. - Abstract: Speed of sound measurements were made in methanol, ethanol, propan-1-ol, and butan-1-ol in the temperature range from (253.15 to 353.15) K at pressures up to 30 MPa by use of a pulse-echo method with a double path type sensor. The expanded overall uncertainty (k = 2) in speed of sound measurements are estimated to be 0.026% for methanol, 0.03% for ethanol, 0.013% for propan-1-ol and 0.01% for butan-1-ol. A double polynomial equation for the speed of sound with inputs of temperature and pressure has been fitted from the experimental results. These were compared with available literature sources and fundamental equations of state, showing good agreement among them to comparable alcohol purities and experimental uncertainties.