Published 1977
| Version v1
Journal article
Investigation of chireal beryllium β-ketoenolates by NMR spectroscopy
Description
The NMR spectra pointed out to a considerable stability of chiral beryllium 3-ketoenolates in solution. The anisochronism of methyl groups was observed in compounds containing the isoporpyl groups. The barrier of topomerization, ΔGsup(=), was estimated at 26-29 kcal/mole. (author)
Additional details
Publishing Information
- Journal Title
- Rocz. Chem.
- Journal Volume
- 51
- Journal Issue
- 11
- Series
- Rocz. Chem.
- Journal Page Range
- 2139-2146
INIS
- Country of Publication
- Poland
- Country of Input or Organization
- Poland
- INIS RN
- 11498978
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALDEHYDES; BERYLLIUM COMPLEXES; CHELATES; CHEMICAL SHIFT; KETONES; MOLECULAR STRUCTURE; NMR SPECTRA; NONAQUEOUS SOLVENTS; NUCLEAR MAGNETIC RESONANCE; STABILITY
- Descriptors DEC
- ALKALINE EARTH METAL COMPLEXES; COMPLEXES; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; RESONANCE; SOLVENTS; SPECTRA