Published October 1, 1984 | Version v1
Journal article

Crossed beam study of reaction of van der Waals molecule O+(NO)2 →NO*2+NO: Angle-resolved chemiluminescence detection

  • 1. Department of Pure and Applied Sciences, The College of Arts and Sciences, The University of Tokyo, Komaba, Meguro-Ku, Tokyo, 153, Japan

Description

Bimolecular reaction of NO dimer with O atom was studied by use of a crossed beam apparatus. NO dimer was generated by the supersonic expansion of NO seeded in He. Oxygen atom beam, generated by the microwave discharge, was crossed with (NO)2 beam and the chemiluminescence from the product NO(2 was measured as a function of the scattering angle. The angular distribution is anisotropic and peaking at theta/sub lab/ = 0, with respect to (NO)2 incidence. This fact suggests sideways or backward scattering of O atom in (NO)2+O reaction

Additional details

Publishing Information

Journal Title
J. Chem. Phys.
Journal Volume
81
Journal Issue
7
Series
J. Chem. Phys.
Journal Page Range
3344-3345
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
16025275
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
ANGULAR DISTRIBUTION; ATOM-MOLECULE COLLISIONS; CHEMILUMINESCENCE; COLLIDING BEAMS; DIMERS; EXPERIMENTAL DATA; NITROGEN OXIDES; OXYGEN
Descriptors DEC
ATOM COLLISIONS; BEAMS; CHALCOGENIDES; COLLISIONS; DATA; DISTRIBUTION; ELEMENTS; EMISSION; INFORMATION; LUMINESCENCE; MOLECULE COLLISIONS; NITROGEN COMPOUNDS; NONMETALS; NUMERICAL DATA; OXIDES; OXYGEN COMPOUNDS; PHOTON EMISSION