Published December 1976
| Version v1
Journal article
Polarographic reduction of uranyl and thorium complexes of methyl-3-mercaptopropionate
Creators
- 1. Malaviya Regional Engineering Coll., Jaipur (India). Dept. of Chemistry
Description
The polarographic reduction of UO22+ and Th4+ ions in methyl-3-mercaptopropionate has been found to be irreversible and diffusion controlled in 0.1 M NaClO4, 0.002% Triton X-100 and 25% ethanol. The values of kinetic parameters-transfer coefficient (αn), formal rate constant (ksub(f,h)deg) for the electrode reaction are determined by Koutecky's method as extended by Meites and Israel. The free energy, enthalpy and entropy of activation have also been reported. (author)
Additional details
Publishing Information
- Journal Title
- J. Indian Chem. Soc.
- Journal Volume
- 53
- Journal Issue
- 12
- Series
- J. Indian Chem. Soc.
- Journal Page Range
- 1192-1193
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 9351559
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL ACTIVATION; ENTHALPY; ENTROPY; FREE ENERGY; ORGANIC SULFUR COMPOUNDS; POLAROGRAPHY; REDUCTION; THORIUM COMPLEXES; URANYL COMPLEXES
- Descriptors DEC
- ACTINIDE COMPLEXES; CHEMICAL REACTIONS; COMPLEXES; ENERGY; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES; URANIUM COMPLEXES
Optional Information
- Notes
- 8 refs.