Published July 2003 | Version v1
Journal article

Excess molar volumes of (benzene + isopropylbenzene, or 1,3,5-trimethylbenzene, or 1,2,4-trimethylbenzene) at temperatures between 298.15 K and 328.15 K

Description

The densities of (benzene + isopropylbenzene, or 1,2,4-trimethylbenzene, or 1,3,5-trimethylbenzene) were measured at temperatures (298.15, 308.15, 318.15, and 328.15) K by means of a vibrating-tube densimeter. The excess molar volumes VmE calculated from the density data provide the temperature dependence of VmE in the temperature range of (298 to 328) K. The VmE results were correlated using the fourth-order Redlich-Kister equation, with the maximum likelihood principle being applied for the determination of the adjustable parameters. It was found that the deviations from ideal behaviour in the systems studied (all being positive) decrease with increasing temperature

Additional details

Identifiers

PII
S0021961403000776;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
35
Journal Issue
7
Journal Page Range
p. 1139-1149
ISSN
0021-9614
CODEN
JCTDAF

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
35018658
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AROMATICS; BENZENE; BINARY MIXTURES; DENSIMETERS; DENSITY; EQUATIONS; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE 0273-0400 K; VOLUME
Descriptors DEC
AROMATICS; DISPERSIONS; HYDROCARBONS; MEASURING INSTRUMENTS; MIXTURES; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; TEMPERATURE RANGE

Optional Information

Copyright
Copyright (c) 2003 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.