Published July 2003
| Version v1
Journal article
Excess molar volumes of (benzene + isopropylbenzene, or 1,3,5-trimethylbenzene, or 1,2,4-trimethylbenzene) at temperatures between 298.15 K and 328.15 K
Creators
Description
The densities of (benzene + isopropylbenzene, or 1,2,4-trimethylbenzene, or 1,3,5-trimethylbenzene) were measured at temperatures (298.15, 308.15, 318.15, and 328.15) K by means of a vibrating-tube densimeter. The excess molar volumes VmE calculated from the density data provide the temperature dependence of VmE in the temperature range of (298 to 328) K. The VmE results were correlated using the fourth-order Redlich-Kister equation, with the maximum likelihood principle being applied for the determination of the adjustable parameters. It was found that the deviations from ideal behaviour in the systems studied (all being positive) decrease with increasing temperature
Additional details
Identifiers
- PII
- S0021961403000776;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 35
- Journal Issue
- 7
- Journal Page Range
- p. 1139-1149
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 35018658
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AROMATICS; BENZENE; BINARY MIXTURES; DENSIMETERS; DENSITY; EQUATIONS; TEMPERATURE DEPENDENCE; TEMPERATURE RANGE 0273-0400 K; VOLUME
- Descriptors DEC
- AROMATICS; DISPERSIONS; HYDROCARBONS; MEASURING INSTRUMENTS; MIXTURES; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; TEMPERATURE RANGE
Optional Information
- Copyright
- Copyright (c) 2003 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.