Targeted and non-target screening of persistent organic pollutants and organophosphorus flame retardants in leachate and sediment from landfill sites in Gauteng Province, South Africa

Highlights: • Target analysis was employed to quantify OCPs, PCBs and OPFRs in landfill leachate and sediment. • Non-target screening was used qualitatively on leachate to identify possible organic contaminants. • High OPFR concentrations confirm their use as replacements of PCBs and PBDEs in waste materials. • First time concentrations of OPFRs in landfill leachate and sediment are reported in South Africa. -- Abstract: In the present study, target analysis and a non-target screening method were employed to investigate the degree of contamination of landfill sediment and leachate in Gauteng Province, South Africa. Polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs), organochlorinated pesticides (OCPs) and organophosphorus flame retardants (OPFRs) were extracted from sediment and leachate samples using solid-liquid extraction and liquid-liquid extraction methods, respectively; and analysed by target analysis using gas chromatography mass spectrometry (GC–MS). Targeted PBDEs were all detected in sediment samples. However, PCBs, CB 52 and CB 101 were below the quantification limit (LOQ) in the sediment samples. The concentrations of OCPs measured ranged from 0.09 ng/g dw (α-HCH) to 5.29 ng/g dw (pp-DDE) in Marie Louis, and from 0.14 ng/g dw (α-HCH) to 11.3 ng/g dw (γ-HCH) in Hatherly, with an average mass fraction of 1.0 (±2.0, SD) ng/g dw in Marie Louis and 2.0 (±3.0, SD) ng/g dw in Hatherly. Among the OPFRs, TnPP, TPTP, T35DMPP and TBPP were below the LOQ in both leachate and sediment samples. Overall, high concentrations of TDCIPP and TCIPP were obtained in both media, ranging from 226 to 14,500 ng/L and 52.0–13,800 ng/L and from 19.6–741 ng/g dw and 32.8–1240 ng/g dw in leachate and sediment, respectively. The high concentrations of certain OPFRs suggest that these may have replaced both PCBs and PBDEs in consumer products currently imported into South Africa. Common compounds identified by non-target screening with high-resolution mass spectrometry of leachate were diethyl [2‑(1, 3‑dioxolan‑2‑yl) ethyl] malonate (C₁₂H₂₀O₆) and 4‑(benzyloxy) cyclohexanone (C₁₃H₂₀O₂). These compounds are possibly associated with plasticizers used in the production of plastic and plastic coatings.