Analysis of the collision-induced absorption spectra of H2 in H2-N2 in the range 5600-9500 cm-1
Creators
- 1. Department of Basic Sciences, Faculty of Engineering Technology, Al-Balqa Applied University, PO Box 15008 Amman 11134 (Jordan)
Description
Enhancement spectra of the collision-induced absorption (CIA) of H2 in the region 5600-9500 cm-1 in binary H2-N2 mixtures were investigated at room temperature for base densities of H2 in the range 89-145 amagat and for partial densities of N2 in the range 30-350 amagat. Enhancement absorption profiles of H2-N2 in the investigated region consist of the superposition of two main parts, the first part is formed of quadrupolar double transitions of the type X1(J) + X1(J) in the range 5600-8500 cm-1 and the second formed of quadrupolar single transitions of the type X2(J) + X0(J) from 7500 to 9500 cm-1, where X is an O(ΔJ = -2), Q(ΔJ = 0) or S(ΔJ = +2) transition. The Birnbaum-Cohen lineshape function was found to give satisfactory fits of the synthetic profiles to the experimental profiles. Lineshape function parameters obtained from the analysis are given
Additional details
Identifiers
- DOI
- 10.1088/0953-4075/40/12/010;
- PII
- S0953-4075(07)46056-4;
Publishing Information
- Journal Title
- Journal of Physics. B, Atomic, Molecular and Optical Physics
- Journal Volume
- 40
- Journal Issue
- 12
- Journal Page Range
- p. 2345-2350
- ISSN
- 0953-4075
- CODEN
- JPAPEH
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 38068746
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ABSORPTION SPECTRA; ENERGY-LEVEL TRANSITIONS; HYDROGEN; LINE WIDTHS; MIXTURES; MOLECULE-MOLECULE COLLISIONS; NITROGEN
- Descriptors DEC
- COLLISIONS; DISPERSIONS; ELEMENTS; MOLECULE COLLISIONS; NONMETALS; SPECTRA