Published June 28, 2007 | Version v1
Journal article

Analysis of the collision-induced absorption spectra of H2 in H2-N2 in the range 5600-9500 cm-1

Creators

  • 1. Department of Basic Sciences, Faculty of Engineering Technology, Al-Balqa Applied University, PO Box 15008 Amman 11134 (Jordan)

Description

Enhancement spectra of the collision-induced absorption (CIA) of H2 in the region 5600-9500 cm-1 in binary H2-N2 mixtures were investigated at room temperature for base densities of H2 in the range 89-145 amagat and for partial densities of N2 in the range 30-350 amagat. Enhancement absorption profiles of H2-N2 in the investigated region consist of the superposition of two main parts, the first part is formed of quadrupolar double transitions of the type X1(J) + X1(J) in the range 5600-8500 cm-1 and the second formed of quadrupolar single transitions of the type X2(J) + X0(J) from 7500 to 9500 cm-1, where X is an O(ΔJ = -2), Q(ΔJ = 0) or S(ΔJ = +2) transition. The Birnbaum-Cohen lineshape function was found to give satisfactory fits of the synthetic profiles to the experimental profiles. Lineshape function parameters obtained from the analysis are given

Additional details

Identifiers

DOI
10.1088/0953-4075/40/12/010;
PII
S0953-4075(07)46056-4;

Publishing Information

Journal Title
Journal of Physics. B, Atomic, Molecular and Optical Physics
Journal Volume
40
Journal Issue
12
Journal Page Range
p. 2345-2350
ISSN
0953-4075
CODEN
JPAPEH

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
38068746
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ABSORPTION SPECTRA; ENERGY-LEVEL TRANSITIONS; HYDROGEN; LINE WIDTHS; MIXTURES; MOLECULE-MOLECULE COLLISIONS; NITROGEN
Descriptors DEC
COLLISIONS; DISPERSIONS; ELEMENTS; MOLECULE COLLISIONS; NONMETALS; SPECTRA