A new ESR dosimeter based on bioglass material

Bioglass (Bio-G) samples were irradiated with 60Co γ-rays to study radicals for dosimetric materials with electron spin resonance (ESR). The ESR spectrum of Bio-G is characterized by two main signals. The first signal at g congruent with 4.3 corresponds to Fe3+ impurities and the second signal at g congruent with 2.0130 with line-width 10.85 G is ascribed as a hole center. The γ-ray dose response and thermal stability were studied to establish the suitability of Bio-G as an ESR dosimeter. A radical formation efficiency, G-value, of 0.53±0.11 was obtained. The lifetime of radicals and the activation energy were estimated from Arrhenius plots to be approximately 255±46 days and 0.71 eV, respectively