Published April 1988
| Version v1
Report
Restricted
Kinetics and mechanisms of elementary chemical processes of importance in combustion. Periodic report 4 for the period October 1987 - April 1988
Description
The rate and mechanism of the reaction of OH with CO have been investigated by pulse radiolysis combined with transient UV-spectrophotometry. At T = 298 K and p = 1 atm. it appears that the low pressure channel (1a) HO + CO -> H + CO2 is much more important than the reaction (1b) HO + CO + M -> HO-C=O + M. At p = 100 - 120 atm wee have observed transient absorption signals in the range of 205 - 240 nm which we tentatively assigned to the collision stabilized HO-C=O adduct. 17 refs. (EG)
Files
Restricted
The record is publicly accessible, but files are restricted to users with access.
Additional details
Additional titles
- Subtitle (English)
- Spectrokinetic studies of the reaction OH + CO
Publishing Information
- Imprint Pagination
- 20 p.
- Report number
- NEI-DK--89
INIS
- Country of Publication
- Denmark
- Country of Input or Organization
- Denmark
- INIS RN
- 19087267
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CHEMICAL REACTION KINETICS; COMBUSTION; HYDROXYL RADICALS; PRESSURE DEPENDENCE; PULSE TECHNIQUES; RADIOLYSIS; ULTRAVIOLET SPECTRA
- Descriptors DEC
- CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; KINETICS; OXIDATION; RADIATION EFFECTS; RADICALS; REACTION KINETICS; SPECTRA
Optional Information
- Contract/Grant/Project number
- Contract EN3E-0095-DK(B)