Published 1982 | Version v1
Journal article Metadata-only

Chelate complexes of iodine (5) fluorides with glycerin and its analogs

Creators

  • 1. AN SSSR, Moscow. Inst. Obshchej i Neorganicheskoj Khimii

Description

Interaction of IF5 with glycerin, α-thioglycerin and guaiacol-glycerin ether in solution of acetonitrite is studied using the NMR 19F method. It is shown that as a result of the reaction chelate isomers IF3(OCH2CHOCH2OH), IF3(OCH2CHOCH2SH) and IF3(OCH2CHOCH2OC6H5OMe) are formed, in which the ligands are bonded with iodine atom through oxygen atoms of neighbouring hydroxyl groups. In the reaction of IF5 with glycerin formation of the bicyclic chelate complex IF2(OCH2CHOCH2O) is also detected, in which all oxygen atoms are bonded with iodine atom

Additional details

Additional titles

Original title (Russian)
Хелатные комплексы фторидов иода (5) с глицерином и его аналогами

Publishing Information

Journal Title
Koord. Khim.
Journal Volume
8
Journal Issue
1
Series
Koord. Khim.
Journal Page Range
55-60
ISSN
0132-344X

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
13695071
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHELATES; CHEMICAL BONDS; CHEMICAL PREPARATION; ETHERS; FLUORIDES; GLYCEROL; IODINE COMPLEXES; NMR SPECTRA; THIOLS
Descriptors DEC
ALCOHOLS; COMPLEXES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; HYDROXY COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; SPECTRA; SYNTHESIS