Published January 2019 | Version v1
Journal article

Synthesis of 4H-chromenes by silver (I)-catalyzed cycloaddition of ortho-quinone methides with N-allenamides

  • 1. Shandong University, Key Laboratory for Colloid and Interface Chemistry of Education Ministry, Department of Chemistry (China)

Description

Chromenes represent an important class of six-membered heterocycles and have drawn tremendous attention in recent years. In this article, we report a convenient and practical synthesis of this heterocycle by a silver (I)-catalyzed cycloaddition reaction between in situ generated ortho-quinone methides and N-allenamides. Diverse 4H-chromenes were synthesized in good to excellent yields under very mild conditions.

Additional details

Identifiers

Publishing Information

Journal Title
Science China. Chemistry (Print)
Journal Volume
62
Journal Issue
1
Journal Page Range
p. 80-86
ISSN
1674-7291

INIS

Country of Publication
China
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
54120137
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BENZOQUINONES; CATALYSIS; SILVER; SYNTHESIS
Descriptors DEC
AROMATICS; ELEMENTS; HYDROCARBONS; METALS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; QUINONES; TRANSITION ELEMENTS

Optional Information

Copyright
Copyright (c) 2019 Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature