Published May 1985
| Version v1
Journal article
Synthesis and structure of Au(OTeF5)3
Creators
- 1. Freie Univ. Berlin (Germany, F.R.). Inst. fuer Anorganische und Analytische Chemie
Description
Stable and crystalline Au(OTeF5)3 is prepared from AuF3 and B(OTeF5)3. The crystal structure analysis of the monoclinic single crystals, space group C2/c, a = 1893.8(4), b = 847.3(2), c'= 564.6(2) pm, β = 94.30(5), gave the OTeF5 positions, but the gold positions only in a statistical manner. Interpretation of weak diffuse super structure reflections resulted in a three times magnified c-axis and produced molecular units of the X2AuX2AuX2 type. This is the first time that bridging OTeF5 ligands have been observed. (author)
Additional details
Additional titles
- Original title (German)
- Synthese und Struktur von Au(OTeF
Publishing Information
- Journal Title
- Z. Anorg. Allg. Chem.
- Journal Volume
- 524
- Series
- Z. Anorg. Allg. Chem.
- Journal Page Range
- 26-32
- ISSN
- 0044-2313
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- German Democratic Republic
- INIS RN
- 16076773
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- BOND ANGLE; EXPERIMENTAL DATA; FLUORIDES; GOLD COMPLEXES; GOLD COMPOUNDS; INTERATOMIC DISTANCES; LATTICE PARAMETERS; LIGANDS; MASS SPECTRA; MONOCLINIC LATTICES; NUCLEAR MAGNETIC RESONANCE; OXYGEN COMPOUNDS; RAMAN SPECTRA; SPACE GROUPS; STRUCTURAL CHEMICAL ANALYSIS; TELLURIUM COMPOUNDS; X-RAY DIFFRACTION
- Descriptors DEC
- COHERENT SCATTERING; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DATA; DIFFRACTION; DISTANCE; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; INFORMATION; MAGNETIC RESONANCE; NUMERICAL DATA; RESONANCE; SCATTERING; SPECTRA; SYMMETRY GROUPS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS