Published November 1997 | Version v1
Journal article Metadata-only

Intersphere hydrogen bond and its effect on structural and energetic characteristics of uranyl nitrate aquacomplex

Creators

  • 1. Belorusskij Gosudarstvennyj Univ., Minsk (Belarus)

Description

Impact of intersphere hydrogen bond on structural and energetic characteristics of water molecules coordinated to uranyl is studied. The effective donor numbers of H2O coordinated molecules are presented and evaluation of the bond enthalpy change to uranyl in various uranyl nitrate aquacomplexes is carried out

Abstract (Russian)

Изучено влияние, оказываемое внешнесферной водородной связью на структурные и энергетические характеристики молекул воды, координированных к уранилу. Приведены эффективные донорные числа координированных молекул Н2О и проведена оценка энтальпии присоединения их к уранилу в различных аквакомплексах уранилнитрата

Additional details

Additional titles

Original title (Russian)
Внешнесферная водородная связь и ее влияние на структурные и энергетические характеристики аквакомплексов уранилнитрата

Publishing Information

Journal Title
Khimicheskaya Fizika
Journal Volume
16
Journal Issue
11
Journal Page Range
p. 11-15
ISSN
0207-401X
CODEN
KHFID9

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
32041123
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AQUEOUS SOLUTIONS; CHEMICAL BONDS; CHEMICAL COMPOSITION; CHEMICAL REACTION KINETICS; COORDINATION VALENCES; CROWN ETHERS; REACTION HEAT; URANYL COMPLEXES; URANYL NITRATES
Descriptors DEC
ACTINIDE COMPLEXES; ACTINIDE COMPOUNDS; COMPLEXES; DISPERSIONS; ENTHALPY; ETHERS; HOMOGENEOUS MIXTURES; KINETICS; MIXTURES; NITRATES; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; REACTION KINETICS; SOLUTIONS; THERMODYNAMIC PROPERTIES; URANIUM COMPLEXES; URANIUM COMPOUNDS; URANYL COMPOUNDS; VALENCE

Optional Information

Notes
17 refs., 2 figs., 1 tab.