Published January 1977
| Version v1
Journal article
Selenium- and tellurium-bridged carbonyl complexes of manganese and rhenium
Description
(CO)5MnBr and (CO)5ReCl react with [(CH3)3Sn]2E (E = Se, Te) to yield the functional di-nuclear complexes [(CO)4M-E-Sn(CH3)3]2 (M = Mn, Re; E = Se, Te). Of these the selenium compounds can be converted into the tetramers [(CO)3M-Se-Sn(CH3)3]4 by heating. Reaction with HCl yields complexes of the type [(CO)4M-EH]2. (orig.)
Abstract (German)
Die Umsetzungen von (CO) 5 MnBr und (CO) 5 ReCl mit [(CH 3 ) 3 Sn] 2 E (E Se, Te) liefern die funktionellen Zweikernkomplexe [(CO) 4 MESn(CH 3 ) 3 ] 2 ( 7, 9 ) (M Mn, Re; E Se, Te). Von diesen lassen sich die Selenverbindungen durch Erhitzen in die Tetrameren [(CO) 3 MSeSn(CH 3 ) 3 ] 4 ( 8 ) überführen. Umsetzung mit HCl führt zu Komplexen des Typs [(CO) 4 MEH] 2 ( 10, 11 ).Additional details
Additional titles
- Original title (German)
- Selen- und Tellur-verbrueckte Carbonylkomplexe des Mangans und Rheniums
Identifiers
Publishing Information
- Journal Title
- Chemische Berichte
- Journal Volume
- 110
- Journal Issue
- 1
- Series
- Chem. Ber.
- Journal Page Range
- 228-236
- ISSN
- 0009-2940
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 8346161
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CARBONYLS; CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; INFRARED SPECTRA; ISOMERS; NUCLEAR MAGNETIC RESONANCE; ORGANOMETALLIC COMPOUNDS; SELENIUM COMPLEXES; TELLURIUM COMPLEXES
- Descriptors DEC
- COMPLEXES; KINETICS; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; REACTION KINETICS; RESONANCE; SPECTRA; SYNTHESIS
Optional Information
- Notes
- 3 tabs.; 27 refs.; Updated automatically by Metadata and Full-Text Enrichment Agent