Published September 11, 1969 | Version v1
Miscellaneous Open

Chromatography of actinides on anion-exchange paper, behaviour of the elements U, Np Pu Am in acid, aqueous and alcohol-water solutions

Creators

Description

A preliminary study of actinide migration on ion exchange paper has been carried out on trace amounts with a view to subsequent application in micro-analysis. The first tests have made it possible to define the factors having an effect on the migrational velocities of aqueous and alcohol-water solutions of HCl and HNO3. The behaviour, of actinides has then been studied in non-saline acid solutions. The results obtained for each element separately are interesting from the point of view of their mutual separation. This analytical technique has finally been applied successfully to the migration of 300 μg of uranium deposited from a 1 ml volume of solution. (author)

Abstract (French)

Une etude preliminaire des migrations d'actinides sur papier echangeur d'ions a ete effectuee a l'echelon traces en vue d'applications micro-analytiques. Les premiers essais ont permis de degager les facteurs influant sur la vitesse de migration des solutions aqueuses et hydroalcooliques de HCl et HNO3. Ensuite, le comportement des actinides a ete etudie, en solutions, acides non salinees. Les resultats obtenus pour chaque element teste isolement, sont interessants en vue de leur separation mutuelle. Cette technique analytique a enfin ete appliquee avec succes a la migration de 300 μg d'uranium deposes a partir d'un volume d'1 ml de solution. (auteur)

Files

46058091.pdf

Files (47.0 MB)

Name Size Download all
md5:793bbd58e7edbcfb12ed588ea7da05d6
47.0 MB Preview Download

Additional details

Additional titles

Original title (French)
Chromatographie des actinides sur papier echangeur d'anions. comportement des elements (U, Np, Pu, Am) dans des milieux acides, aqueux et hydroalcooliques

Identifiers

URL
http://www.iaea.org/inis/Contacts/;

Publishing Information

Imprint Pagination
29 p.
Report number
CEA-N--1210

INIS

Country of Publication
France
Country of Input or Organization
France
INIS RN
46058091
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AUTORADIOGRAPHY; ETHANOL; HYDROCHLORIC ACID; ION EXCHANGE CHROMATOGRAPHY; NEPTUNIUM; NITRIC ACID; PAPER; PH VALUE; PLUTONIUM; SOLVENTS; URANIUM; VALENCE
Descriptors DEC
ACTINIDES; ALCOHOLS; CHLORINE COMPOUNDS; CHROMATOGRAPHY; ELEMENTS; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; HYDROXY COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; METALS; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; SEPARATION PROCESSES; TRANSURANIUM ELEMENTS

Optional Information

Notes
10 refs.; Available from the INIS Liaison Officer for France, see the 'INIS contacts' section of the INIS website for current contact and E-mail addresses: http://www.iaea.org/inis/Contacts/