Published February 2009
| Version v1
Journal article
System on the basis of compounds A2TeC6 (A=K, Rb, Cs, Tl(I); C=Br, I) with peritectic type of interaction
Creators
- 1. Uzhgorodskij Natsional'nyj Univ, Uzhgorod (Ukraine)
Description
Phase equilibriums in six quasibinary systems consisting of various combinations of compounds K2TeI6-Cs2TeI6, Rb2TeI6-Cs2TeI6, K2TeI6-Rb2TeI6, K2TeBr6-Tl2TeBr6, Rb2TeBr6-Tl2TeBr6, Cs2TeBr6-Tl2TeBr6 have been studied by DTA and X-ray phase analysis. Peritectic type of interaction between components with the formation of broad areas of solid solutions on the basis of initial ternary halides was established for all systems. Trend to an increase in melting and crystallization points of solid solutions is noted. This is due to substitution of smaller ions A' by larger ones contributing to the stabilization of crystal structures of ternary halides appropriate forming solid solutions
Abstract (Russian)
@@@@@@@@ @@@ @ @@@ @@@@@@@ @@@@@@@ @@@@@@@@@@ @ @@@@@ @@@@@@@@@@@@@ @@@@@@@@, @@@@@@@@@ @@ @@@@@@@@@ @@@@@@@@@@ @@@@@@@@@@ K2TeI6-Cs2TeI6, Rb2TeI6-Cs2TeI6, K2TeI6-Rb2TeI6, K2TeBr6-Tl2TeBr6, Rb2TeBr6-Tl2TeBr6, Cs2TeBr6-Tl2TeBr6. @@@ @@@@ @@@@@@ @@@@@@@@@@ @@@@@@@@@@@@@@@ @@@ @@@@@@@@@@@@@@ @@@@@@@@@@@ @ @@@@@@@@@@@@ @@@@@@@ @@@@@@@@ @@@@@@@ @@@@@@@@@ @@ @@@@@@ @@@@@@@@ @@@@@@@ @@@@@@@@@@@. @@@@@@@@ @@@@@@@@@ @ @@@@@@@@@@@ @@@@@@@@@@ @@@@@@@@@ @ @@@@@@@@@@@@@@ @@@@@@@ @@@@@@@@@, @@@ @@@@@@@@@@@ @@@@@@@@@@ @@@@@@@ @@@@@ @' @@@@@ @@@@@@@@, @@@@@@@@@@@@@@@ @@@@@@@@@@@@ @@@@@@@@@@@@@@@ @@@@@@@@ @@@@@@@ @@@@@@@@@@@, @@@@@@@@@@ @@@@@@@@@@@@@@@ @@@@@@@ @@@@@@@@Additional details
Additional titles
- Original title (Russian)
- Системы на основе соединений А
Publishing Information
- Journal Title
- Zhurnal Neorganicheskoj Khimii
- Journal Volume
- 54
- Journal Issue
- 2
- Journal Page Range
- p. 360-363
- ISSN
- 0044-457X
- CODEN
- ZNOKAQ
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 41121494
- Subject category
- S36: MATERIALS SCIENCE; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CESIUM BROMIDES; CESIUM IODIDES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CRYSTALLIZATION; DIFFERENTIAL THERMAL ANALYSIS; MELTING POINTS; PHASE DIAGRAMS; POTASSIUM IODIDES; RUBIDIUM IODIDES; SOLID SOLUTIONS; TELLURIUM BROMIDES; TELLURIUM IODIDES; X-RAY DIFFRACTION
- Descriptors DEC
- ALKALI METAL COMPOUNDS; BROMIDES; BROMINE COMPOUNDS; CESIUM COMPOUNDS; COHERENT SCATTERING; DIAGRAMS; DIFFRACTION; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; INFORMATION; INORGANIC PHOSPHORS; IODIDES; IODINE COMPOUNDS; MIXTURES; PHASE TRANSFORMATIONS; PHOSPHORS; PHYSICAL PROPERTIES; POTASSIUM COMPOUNDS; RUBIDIUM COMPOUNDS; SCATTERING; SOLUTIONS; SYNTHESIS; TELLURIUM COMPOUNDS; TELLURIUM HALIDES; THERMAL ANALYSIS; THERMODYNAMIC PROPERTIES; TRANSITION TEMPERATURE
Optional Information
- Notes
- 8 refs., 2 figs.