Published February 1985
| Version v1
Journal article
Synthesis of 10H-dibenz[b, e]Chlorinium borofluoride and deuterium exchange reaction in CHΛ2-group of cations of 10H-dibenz[b, e]Halogeninium
- 1. Moskovskij Gosudarstvennyj Univ. (USSR)
- 2. AN SSSR, Moscow. Inst. Ehlementoorganicheskikh Soedinenij
Description
10H-dibenz[b, e]chlorinium borofluoride has been syntheized. Influence of halogeninium atom on another bridge group - CH2-group of cations of 10H-dibenz[b, e]halogeninium is studied. By means of deuterium exchange reactions it is shown, that CH-acidity of methylene group of the above-mentioned cations increases in the series I+ < Br+ < Cl+. Existence of covalent form of 10H-dibenz[b, e]iodinium hydroxide is recorded and products of its radical decomposition are investigated
Additional details
Additional titles
- Original title (Russian)
- Синтез борфторида 10H-дибенз[б, е] хлориния и реакция дейтерообмена в CHΛ2-звене катионов 10H-дибенз[б, е]Галогениниев
Publishing Information
- Journal Title
- Zh. Prikl. Spektrosk.
- Journal Issue
- no.6
- Series
- Zh. Prikl. Spektrosk.
- ISSN
- 0514-7506
- CODEN
- ZPSBA
INIS
- Country of Publication
- Belarus
- Country of Input or Organization
- USSR
- INIS RN
- 17021271
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AROMATICS; BORON COMPLEXES; CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; DEUTERIUM COMPOUNDS; FLUORIDES; HYDROXIDES; IODINE COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; REACTION INTERMEDIATES
- Descriptors DEC
- COMPLEXES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; KINETICS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; REACTION KINETICS; SYNTHESIS
Optional Information
- Notes
- For English translation see the journal Journal of Applied Spectroscopy (USA).