Published 2017
| Version v1
Book
Liquid chromatographic studies on the retention behaviour of Pu(III), Pu(IV) and Pu(VI) in presence of Mandelic acid eluent
Creators
- 1. Fuel Chemistry Division, Bhabha Atomic Research Centre, Mumbai (India)
Description
Liquid chromatographic separation of plutonium (Pu) oxidation states viz. Pu(III), Pu(IV) and Pu(VI) was investigated using mandelic acid as an eluent. Chromatographic parameters such as concentration of eluent, pH of the mobile phase and methanol content in the mobile phase etc. were studied using a monolith C18 stationary phase. Under low pH conditions, Pu(IV) showed more retention than Pu(VI) but the pattern was reversed at higher pH (>3.5) conditions. Based on these studies a mobile phase composition consisting of 0.15 M mandelic acid of pH 3 and 20% (v/v) methanol was used for the separation of Pu species. (author)
Additional details
Publishing Information
- Publisher
- Bhabha Atomic Research Centre
- Imprint Place
- Mumbai (India)
- ISBN
- 81-8372-080-3
- Imprint Title
- Proceedings of the thirteenth DAE-BRNS nuclear and radiochemistry symposium
- Imprint Pagination
- 750 p.
- Journal Page Range
- p. 402-403
Conference
- Title
- 13. DAE-BRNS nuclear and radiochemistry symposium
- Acronym
- NUCAR-2017
- Dates
- 6-10 Feb 2017
- Place
- Bhubaneswar (India)
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 48053941
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- LIQUID COLUMN CHROMATOGRAPHY; MANDELIC ACID; NITRIC ACID; PH VALUE; PLUTONIUM
- Descriptors DEC
- ACTINIDES; CARBOXYLIC ACIDS; CHROMATOGRAPHY; ELEMENTS; HYDROGEN COMPOUNDS; HYDROXY ACIDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; METALS; NITROGEN COMPOUNDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; SEPARATION PROCESSES; TRANSURANIUM ELEMENTS
Optional Information
- Notes
- 4 refs., 3 figs.