Published December 1985
| Version v1
Journal article
Thermodynamic study of solid solutions, (0,87-y)ZrO2xyHfO2x0,13CaO
Creators
- 1. Moskovskij Gosudarstvennyj Univ. (USSR). Khimicheskij Fakul'tet
Description
Partial thermodynamic oxygen properties and ion transfer numbers of solid solutions Zrsub(0.87-y)Hfsub(y)Casub(0.13)Osub(1.870-x) are determined by electromotive force method with a solid electrolyte. It is shown that HfO2 addition to the solid solution Zrsub(0.87)Casub(0.13)Osub(1.870-x) contributes to thermodynamic stability increase and expands oxygen pressures area, in which this solid solution practically preserves purely anion conductivity
Additional details
Additional titles
- Original title (Russian)
- Термодинамическое исследование твердых растворов (0,87-ы)ZrO
Publishing Information
- Journal Title
- Zh. Fiz. Khim.
- Journal Volume
- 59
- Journal Issue
- 12
- Series
- Zh. Fiz. Khim.
- Journal Page Range
- 2922-2925
- ISSN
- 0044-4537
- CODEN
- ZFKHA
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 18001255
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CALCIUM OXIDES; CHEMICAL COMPOSITION; ELECTROLYTIC CELLS; ELECTROMOTIVE FORCE; ENTHALPY; ENTROPY; HAFNIUM OXIDES; OXYGEN POTENTIAL; SOLID ELECTROLYTES; SOLID SOLUTIONS; TEMPERATURE DEPENDENCE; TRANSFER NUMBERS; VERY HIGH TEMPERATURE; ZIRCONIUM OXIDES
- Descriptors DEC
- ALKALINE EARTH METAL COMPOUNDS; CALCIUM COMPOUNDS; CHALCOGENIDES; DISPERSIONS; ELECTRIC POTENTIAL; ELECTROLYTES; ENERGY; FREE ENTHALPY; HAFNIUM COMPOUNDS; HOMOGENEOUS MIXTURES; MIXTURES; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SOLUTIONS; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPOUNDS; ZIRCONIUM COMPOUNDS
Optional Information
- Notes
- For English translation see the journal Russian Journal of Physical Chemistry (UK).