Published January 2019
| Version v1
Journal article
High Pressure, Temperature, and Solvent Effects on the Rate of the Diels-Alder Reaction of Furan with N-Phenylmaleimide
- 1. Kazan (Volga Region) Federal University, Butlerov Institute of Chemistry (Russian Federation)
Description
The effects of temperature, solvent nature, and high pressure on the rate of the Diels-Alder reaction of furan with N-phenylmaleimide were studied. A weak acceleration of the title reaction in proton-donor media was observed in comparison to other cycloaddition and ene reactions. The volumes of activation and reaction coincided within the experimental error, in keeping with the presumed cyclic transition state.
Additional details
Identifiers
Publishing Information
- Journal Title
- Russian Journal of Organic Chemistry
- Journal Volume
- 55
- Journal Issue
- 1
- Journal Page Range
- p. 7-10
- ISSN
- 1070-4280
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 51108821
- Subject category
- S46: INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ACCELERATION; DIELS-ALDER REACTION; ERRORS; FURANS; HYDROSTATICS; PRESSURE RANGE MEGA PA 10-100; PROTONS; SOLVENTS
- Descriptors DEC
- BARYONS; CHEMICAL REACTIONS; CYCLIZATION; ELEMENTARY PARTICLES; FERMIONS; HADRONS; HETEROCYCLIC COMPOUNDS; NUCLEONS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PRESSURE RANGE; PRESSURE RANGE MEGA PA
Optional Information
- Copyright
- Copyright (c) 2019 Pleiades Publishing, Ltd.