Published 1994 | Version v1
Book

High-temperature dissociation pressure of silicon nitride

  • 1. Inst. for New Chemical Problems, Russian Academy of Sciences, Chernogolovka (Russian Federation)
  • 2. Scientific-Research Inst. ''Lutch'', Podolosk (Russian Federation)

Description

Parameters of the Si3N4 dissociation pressure at 1350 -2000 C were obtained by the Knudsen technique for three types of powders with different admixtures level. As a whole, the nitrogen pressure was observed to increase with increasing the oxygen content. However, this dependence was not constant at all temperatures for the investigated powders. From the information on the dissociation the values of the enthalphy and Gibbs free energy of Si3N4 formation were evaluated and discussed. This discussion has revealed that our results for the powder III (1.25%O) and especially one II (1.6 wt%O) seem very reliable. (orig.)

Part of:
Silicon nitride 93

Additional details

Publishing Information

Publisher
Trans Tech Publ.
Imprint Place
Aedermannsdorf (Switzerland)
ISBN
0-87849-668-8
Imprint Title
Silicon nitride 93
Imprint Pagination
782 p.
Journal Volume
89-91
Series
Key Engineering Materials.
Journal Page Range
p. 369-372.
ISSN
1013-9826
CODEN
KEMAEY

Conference

Title
International conference on silicon nitride-based ceramics.
Dates
4-6 Oct 1993.
Place
Stuttgart (Germany).

INIS

Country of Publication
Switzerland
Country of Input or Organization
Switzerland
INIS RN
25057798
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Conference
Descriptors DEI
DISSOCIATION; FREE ENERGY; FREE ENTHALPY; NITROGEN; OXYGEN; POWDERS; PRESSURE DEPENDENCE; SILICON NITRIDES; TEMPERATURE DEPENDENCE
Descriptors DEC
ELEMENTS; ENERGY; NITRIDES; NITROGEN COMPOUNDS; NONMETALS; PHYSICAL PROPERTIES; PNICTIDES; SILICON COMPOUNDS; THERMODYNAMIC PROPERTIES

Optional Information