Substitutional chemistry of MAPbI${}_3$. Gaining control over material photostability and photovoltaic performance via Pb${}^{2+}$ replacement

The strategy of partial Pb${}^{2+}$ substitution is applied, in prototypical MAPbI${}_3$ perovskite, with a large array of metal cations in order to comprehensively explore their possible incorporation in the perovskite lattice at Pb${}^{2+}$ sites and thus obtain improved photostability of the absorber. An analysis of lattice parameters and optoelectronic properties of MAPb${}_{1-x}$M${}_x$I${}_{\sim 3}$ compositions allowed authors to deduce which metal cations are partially incorporated in the perovskite structure and which are expelled in the form of secondary phases. Curious effects of metal incorporation are observed, such as a decrease in the tetragonal distortion ratio and a change in the band gap. This work reveals that the doping of 11 metal cations significantly improves the photostability of the MAPbI${}_3$ films. Multiple MAPb${}_{1-x}$M${}_x$I${}_{\sim 3}$ formulations deliver superior power conversion efficiencies (PCEs) in solar cells. The DFT calculations further demonstrate a complex relationship between the synthetic conditions and doping patterns. The performed study is thus a stepping stone in the development of more stable perovskite absorbers with superior photovoltaic properties. (© 2024 Wiley‐VCH GmbH)