Effect of high absorbed radiation doses on transformation depth of CO2-H2S mixture

A study was made on kinetics of accumulation of radiolysis products of CO2-HS mixture and their effect on the form of kinetic curves at high absorbed radiation doses. Irradiation of CO2-H2S mixture was conducted under static conditions at CO60 γ-plant. The obtained results enabled to conclude, that partial substitution of one source of oxidative particles (H2O) for redistribution both of rates of CO and H2 formation and hydrogen sulfide oxidation, took place during radiolysis of CO2-H2S mixtures with increase of absorbed dose. This results to convergence of CO and H2 concentrations at high absorbed radiation doses