Published May 1985
| Version v1
Journal article
Preparation of tris(3-substituted acetylacetonato)ruthenium(III) complexes and their electrochemical behavior in acetonitrile
Creators
- 1. Jochi Univ., Tokyo (Japan). Faculty of Science and Technology
Description
Four tris(3-substituted acetylacetonato)ruthenium(III) complexes were newly synthesized and their electrochemical oxidation and reduction were investigated in acetonitrile. The oxidation and reduction potentials of [RuIII(R'-CO-CR-CO-R'')3] can be expressed as a linear function of the sum of the Hammett constants, if one uses the para-position value for R and the meta-position values for R' and R''. (author)
Additional details
Publishing Information
- Journal Title
- Chem. Lett. (Tokyo)
- Journal Volume
- 1985
- Journal Issue
- 5
- Series
- Chem. Lett. (Tokyo).
- Journal Page Range
- 581-584
- ISSN
- 0366-7022
- CODEN
- CMLTA
INIS
- Country of Publication
- Japan
- Country of Input or Organization
- Japan
- INIS RN
- 18030609
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ACETONITRILE; CHEMICAL PREPARATION; ELECTROCHEMISTRY; KETONES; ORGANIC BROMINE COMPOUNDS; ORGANIC CHLORINE COMPOUNDS; ORGANIC IODINE COMPOUNDS; REDOX POTENTIAL; RUTHENIUM COMPLEXES
- Descriptors DEC
- COMPLEXES; NITRILES; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES