Solution processed Copper Phthalocyanine nanowires: A promising supercapacitor anode material
Creators
- 1. School of Materials Science & Nanotechnology, Jadavpur University, Kolkata 700032 (India)
- 2. Department of Electronics & Telecommunication Engineering, Jadavpur University, Kolkata 700032 (India)
- 3. Thin Film and Nanoscience Lab, Department of Physics, Jadavpur University, Kolkata 700032 (India)
- 4. Department of Industrial Chemistry & Swami Vivekananda Research Centre, Ramakrishna Mission Vidyamandira, Belur Math, Howrah 711202 (India)
- 5. Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032 (India)
Description
In this paper, Copper Phthalocyanine (CuPc) nanostructures are the focus of an electrochemical investigation. This Phthalocyanine is nitrogen enriched having metal redox centers that facilitate the redox reaction. CuPc nanowires are synthesized by a simple room temperature process from bulk CuPc powder and their electrochemical properties are explored for the first time. The as prepared samples are characterized by X-ray Diffraction, high resolution transmission electron microscopy, field emission scanning electron microscopy, etc. They are then tested electrochemically in a three electrode system. Cyclic voltammogram (CV) and charge discharge (CD) profiles have been recorded. The CuPc nanowire electrode exhibits 406 F/g capacitance at 5 mVS−1 scan rate and 260 F/g at 0.3 A/g current density. Long cycling stability up to 3000 cycles at 6 A/g has been carried out. The results show that this material can be used as the potential candidate for positive electrode in supercapacitor applications.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.physe.2019.113654Additional details
Identifiers
- DOI
- 10.1016/j.physe.2019.113654;
- PII
- S1386947719304886;
Publishing Information
- Journal Title
- Physica E. Low-Dimensional Systems and Nanostructures (Print)
- Journal Volume
- 114
- Journal Page Range
- vp.
- ISSN
- 1386-9477
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 54126046
- Subject category
- S77: NANOSCIENCE AND NANOTECHNOLOGY;
- Descriptors DEI
- ANODES; CAPACITANCE; CAPACITIVE ENERGY STORAGE EQUIPMENT; COPPER COMPLEXES; ELECTROCHEMISTRY; FIELD EMISSION; METALS; NANOWIRES; NITROGEN; PHTHALOCYANINES; POWDERS; REDOX REACTIONS; SCANNING ELECTRON MICROSCOPY; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION
- Descriptors DEC
- CHEMICAL REACTIONS; CHEMISTRY; COHERENT SCATTERING; COMPLEXES; DIFFRACTION; DYES; ELECTRICAL PROPERTIES; ELECTRODES; ELECTRON MICROSCOPY; ELEMENTS; EMISSION; EQUIPMENT; HETEROCYCLIC COMPOUNDS; MICROSCOPY; NANOSTRUCTURES; NONMETALS; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; SCATTERING; TRANSITION ELEMENT COMPLEXES
Optional Information
- Copyright
- Copyright (c) 2019 Elsevier B.V. All rights reserved.