Physical properties of systems of interest to the edible oil industry: Viscosities and densities of model systems formed by (triacylglycerol + fatty acid + solvent)
Description
Highlights: • Physical properties are essential for equipment design. • Physical properties of systems from edible oils and biodiesel were measured. • Densities and viscosities data were used to test estimate capability of simple models. - Abstract: The knowledge of transport properties is fundamental for the design of equipment, pipes, pumps and other accessories involved in the oil and fat industry. This work reports a database of viscosities and densities for 64 model systems formed by (triacylglycerol + fatty acid + solvent) applying different temperatures and concentrations, leading to a total of 674 experimental data points of each property. In order to test an equation that allows a simple and direct estimation, density and viscosity experimental values were estimated using Kay's mixing rules in its simple form; viscosities were also estimated using modified Kay's mixing rules. Density estimation results in average relative deviations (ARD) less than 1%. In the case of viscosities, at least one of the variations of the model resulted in an ARD less than 10%. These results may be an important tool to understand the thermodynamic behaviour of mixtures containing fatty compounds and solvents, which imply improvement in the production of edible oils and biodiesel.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jct.2017.06.012Additional details
Identifiers
- DOI
- 10.1016/j.jct.2017.06.012;
- PII
- S0021-9614(17)30216-1;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 113
- Journal Page Range
- p. 198-212
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 49072402
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- BIODIESEL FUELS; CARBOXYLIC ACIDS; DENSITY; EXPERIMENTAL DATA; INDUSTRY; OILS; SOLVENTS; VISCOSITY
- Descriptors DEC
- ALTERNATIVE FUELS; BIOFUELS; DATA; FUELS; INFORMATION; LIQUID FUELS; NUMERICAL DATA; ORGANIC ACIDS; ORGANIC COMPOUNDS; OTHER ORGANIC COMPOUNDS; PHYSICAL PROPERTIES
Optional Information
- Copyright
- Copyright (c) 2017 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.