Published October 2017 | Version v1
Journal article

Physical properties of systems of interest to the edible oil industry: Viscosities and densities of model systems formed by (triacylglycerol + fatty acid + solvent)

Description

Highlights: • Physical properties are essential for equipment design. • Physical properties of systems from edible oils and biodiesel were measured. • Densities and viscosities data were used to test estimate capability of simple models. - Abstract: The knowledge of transport properties is fundamental for the design of equipment, pipes, pumps and other accessories involved in the oil and fat industry. This work reports a database of viscosities and densities for 64 model systems formed by (triacylglycerol + fatty acid + solvent) applying different temperatures and concentrations, leading to a total of 674 experimental data points of each property. In order to test an equation that allows a simple and direct estimation, density and viscosity experimental values were estimated using Kay's mixing rules in its simple form; viscosities were also estimated using modified Kay's mixing rules. Density estimation results in average relative deviations (ARD) less than 1%. In the case of viscosities, at least one of the variations of the model resulted in an ARD less than 10%. These results may be an important tool to understand the thermodynamic behaviour of mixtures containing fatty compounds and solvents, which imply improvement in the production of edible oils and biodiesel.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jct.2017.06.012

Additional details

Identifiers

DOI
10.1016/j.jct.2017.06.012;
PII
S0021-9614(17)30216-1;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
113
Journal Page Range
p. 198-212
ISSN
0021-9614
CODEN
JCTDAF

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
49072402
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
BIODIESEL FUELS; CARBOXYLIC ACIDS; DENSITY; EXPERIMENTAL DATA; INDUSTRY; OILS; SOLVENTS; VISCOSITY
Descriptors DEC
ALTERNATIVE FUELS; BIOFUELS; DATA; FUELS; INFORMATION; LIQUID FUELS; NUMERICAL DATA; ORGANIC ACIDS; ORGANIC COMPOUNDS; OTHER ORGANIC COMPOUNDS; PHYSICAL PROPERTIES

Optional Information

Copyright
Copyright (c) 2017 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.