Remote determination of oxygen and water at millimetre wave frequencies using a fibre optic communications network
Description
This paper describes the development of a remote millimetre wave (MMW) spectrometer capable of operation in the 57-66, 114-128 and 171-189 GHz bands. A 9.5-10.5 GHz signal from a yttrium iron garnet (YIG) source is carried via an infrared (IR) laser down a 1 km fibre-optic cable using a high-speed communications modulator. The 6th harmonic of the transmitted microwave signal is generated directly with an active sextrupler, which permits working in the 57-66 GHz band. For operation at 114-128 and 171-189 GHz, the 57-66 GHz output from the sextrupler is doubled or tripled by a further harmonic generator. Absorption line strength measurements and hence sample concentration determinations are undertaken using a Fabry-Perot cavity absorption cell. The spectroscopic data are recovered from the remote spectrometer by transmitting the rectified signal back over a further fibre-optic cable. Also described are the methods of cavity stabilisation and control across this fibre optic network. Oxygen determinations in the 57-66 and 114-128 GHz bands are performed to evaluate the performance of the spectrometer. A determination of water vapour in air at atmospheric pressure, at 183 GHz, is also presented, over a range of ∼5x10-5 to ∼0.025 volume fraction in air
Additional details
Identifiers
- PII
- S0003267002013648;
Publishing Information
- Journal Title
- Analytica Chimica Acta
- Journal Volume
- 476
- Journal Issue
- 1
- Journal Page Range
- p. 25-32
- ISSN
- 0003-2670
- CODEN
- ACACAM
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 36108439
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ABSORPTION; AIR; ATMOSPHERIC PRESSURE; FERRITE GARNETS; GHZ RANGE 01-100; GHZ RANGE 100-1000; OXYGEN; PERFORMANCE; SPECTROMETERS; SPECTROSCOPY; WATER; WATER VAPOR; YTTRIUM COMPOUNDS
- Descriptors DEC
- ELEMENTS; FLUIDS; FREQUENCY RANGE; GASES; GHZ RANGE; HYDROGEN COMPOUNDS; MEASURING INSTRUMENTS; MINERALS; NONMETALS; OXIDE MINERALS; OXYGEN COMPOUNDS; SORPTION; TRANSITION ELEMENT COMPOUNDS; VAPORS
Optional Information
- Copyright
- Copyright (c) 2002 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.