Published 2003
| Version v1
Journal article
On the new unexpected benzoxazino-benzoxazine derivative
- 1. Institute of Chemistry and Environmental Protection, Technical University, Szczecin (Poland)
- 2. Faculty of Chemistry, University of Wroclaw, Wroclaw (Poland)
Description
The reaction between 2-amino-5-nitrophenol and 1,2-cyclohexadione in ethanol leads to formation, in addition to corresponding propellane of the compounds. The X-ray diffraction, NMR and IR studies allowed to solve the structure of molecules. It has been shown that planar nitrobenzoxazine groups are oriented to each other perpendicularly with a chair conformation of the carbohexyl unit. The possible mechanism or reaction is discussed. (author)
Additional details
Additional titles
- Augmented title (English)
- NMR study
Publishing Information
- Journal Title
- Polish Journal of Chemistry
- Journal Volume
- 77
- Journal Issue
- 11
- Journal Page Range
- p. 1419-1426
- ISSN
- 0137-5083
INIS
- Country of Publication
- Poland
- Country of Input or Organization
- Poland
- INIS RN
- 35078107
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- AMINES; BENZOXAZOLES; BOND ANGLE; BOND LENGTHS; CHEMICAL BONDS; CRYSTAL STRUCTURE; EXPLOSIVES; HYDROGEN; INFRARED SPECTRA; LATTICE PARAMETERS; MOLECULAR STRUCTURE; NITROPHENOL; NMR SPECTRA; SOLUTIONS; X-RAY DIFFRACTION
- Descriptors DEC
- AROMATICS; AZOLES; COHERENT SCATTERING; DIFFRACTION; DIMENSIONS; DISPERSIONS; ELEMENTS; HETEROCYCLIC COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROXY COMPOUNDS; LENGTH; MIXTURES; NITRO COMPOUNDS; NONMETALS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; OXAZOLES; PHENOLS; SCATTERING; SPECTRA
Optional Information
- Notes
- 18 refs, 1 fig., 3 tabs, 1 scheme