Published April 2019 | Version v1
Journal article

Enthalpies of Anion Exchange of Chloride by Pyridinecarboxylate in AV-17-8 Anionite

  • 1. Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences (Russian Federation)

Description

Enthalpies of Cl anion exchange for anions of nicotinic, isonicotinic, dipicolinic, and cinchomeronic acids on the strongly basic anionite AV-17-8 are measured at 298 K by means of microcalorimetry. Partial and standard enthalpies of sorption of pyridinecarboxylic acid anions on the Cl-form of AV-17-8 anionite from aqueous solutions are determined. The values of standard enthalpies lie in the range 3–14 kJ/mol, increasing in the order nicotinate, isonicotinate, dipicolinic acid anions, and cinchomeronic acid anions.

Additional details

Identifiers

Publishing Information

Journal Title
Russian Journal of Physical Chemistry
Journal Volume
93
Journal Issue
4
Journal Page Range
p. 743-747
ISSN
0036-0244
CODEN
RJPCAR

INIS

Country of Publication
Russian Federation
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
52006512
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ANIONS; AQUEOUS SOLUTIONS; CALORIMETRY; CHLORIDES; CHLORINE IONS; ENTHALPY; ION EXCHANGE
Descriptors DEC
CHARGED PARTICLES; CHLORINE COMPOUNDS; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; IONS; MIXTURES; PHYSICAL PROPERTIES; SOLUTIONS; THERMODYNAMIC PROPERTIES

Optional Information

Copyright
Copyright (c) 2019 Pleiades Publishing, Ltd.