Published March 2007 | Version v1
Journal article Metadata-only

Elastic peak of K shell excited HCl molecule: Comparison HCl-DCl-Experiment and theory

Creators

  • 1. Laboratoire de Chimie Physique-Matiere et Rayonnement, UMR 7614, 11 Rue Pierre et Marie Curie, 75231 Paris Cedex 05 (France)
  • 2. Department of Chemistry, University of Nevada, Las Vegas, NV (United States)
  • 3. Theoretical Chemistry, Roslagstullsbacken 15, Royal Institute of Technology, S-106 91 Stockholm (Sweden)

Description

Femtosecond dynamics has been recently observed by resonant X-ray Raman scattering (RXRS) after excitation along the dissociative Cl 1s→6σ* resonance of gas phase HCl. In this paper, we show a method to take into account and correct for self-absorption of the elastic peak, in order to allow for quantitative comparison with theory. We have performed measurements on the DCl molecule exhibiting ultrafast nuclear motion. A comparison between HCl and DCl is presented

Additional details

Identifiers

DOI
10.1016/j.elspec.2006.11.007;
PII
S0368-2048(06)00155-1;

Publishing Information

Journal Title
Journal of Electron Spectroscopy and Related Phenomena
Journal Volume
155
Journal Issue
1-3
Journal Page Range
p. 91-94
ISSN
0368-2048
CODEN
JESRAW

Conference

Title
International symposium on scattering, coincidence and absorption studies of molecules (SCASM)
Dates
4-6 Sep 2006
Place
Rio de Janeiro (Brazil)

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
39083185
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Conference
Descriptors DEI
COMPARATIVE EVALUATIONS; EXCITATION; HYDROCHLORIC ACID; K SHELL; MOLECULES; PEAKS; RAMAN EFFECT; RESONANCE; SELF-ABSORPTION; X RADIATION
Descriptors DEC
ABSORPTION; CHLORINE COMPOUNDS; ELECTROMAGNETIC RADIATION; ELECTRONIC STRUCTURE; ENERGY-LEVEL TRANSITIONS; EVALUATION; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; IONIZING RADIATIONS; RADIATIONS; SORPTION

Optional Information

Copyright
Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.