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Published March 2020 | Version v1
Journal article

Calculation of the Distribution Coefficient for Sr2+ in LaF3 Crystal at Infinite Dilution, Based on the Data on Directional Solidification of La1 − ySryF3 − y Solid Solutions

  • 1. Shubnikov Institute of Crystallography, Federal Scientific Research Centre "Crystallography and Photonics," Russian Academy of Sciences (Russian Federation)

Description

The thermodynamic distribution coefficient for Sr2+ impurity in LaF3 crystal at infinite dilution (c → 0) k0 = 1.60 ± 0.02 is determined based on the data on directional solidification of La1 − ySryF3 − y solid solutions (0.01 ≤ y ≤ 0.15, LaF3 tysonite structure type). The obtained k0 value is in good agreement with the estimated distribution coefficient k0 = 1.7, which was found previously by modified cryoscopy from the liquid–solid phase diagram of the SrF2–LaF3 system.

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Identifiers

Publishing Information

Journal Title
Crystallography Reports
Journal Volume
65
Journal Issue
2
Journal Page Range
p. 297-299
ISSN
1063-7745
CODEN
CYSTE3

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Copyright
Copyright (c) 2020 © Pleiades Publishing, Inc. 2020