Published 1984 | Version v1
Journal article Metadata-only

The relaxed triplet state of the 1,2,4,5,-tetracyanobenzene-benzene complex

Creators

  • 1. Naval Research Lab., Washington, DC (USA)
  • 2. Manchester Univ. (UK). Dept. of Chemistry

Description

The triplet state of the tetracyanobenzene-benzene complex has been produced by pulse radiolysis. The observation of a triplet energy transfer equilibrium between this complex and benzophenone has established a relaxed triplet energy of 65.5 +- 0.15 kcal mol-1 for the complex. This shows that relaxation from the Franck-Condon state is negligible. (author)

Additional details

Additional titles

Subtitle (English)
Triplet energy transfer equilibration with benzophenone

Publishing Information

Journal Title
Radiat. Phys. Chem.
Journal Volume
23
Journal Issue
1-2
Series
Radiat. Phys. Chem.
Journal Page Range
111-115
ISSN
0146-5724

INIS

Country of Publication
United Kingdom
Country of Input or Organization
United Kingdom
INIS RN
15020598
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
ABSORPTION SPECTRA; BENZENE; BENZOPHENONE; CHEMICAL REACTION KINETICS; COMPLEXES; DECAY; ELECTRONS; ENERGY TRANSFER; EQUILIBRIUM; EXPERIMENTAL DATA; FRANCK-CONDON PRINCIPLE; ORGANIC NITROGEN COMPOUNDS; PULSES; RADIOLYSIS; RELAXATION; TRANSIENTS; TRIPLETS
Descriptors DEC
AROMATICS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DATA; DECOMPOSITION; ELEMENTARY PARTICLES; FERMIONS; HYDROCARBONS; INFORMATION; KETONES; KINETICS; LEPTONS; MULTIPLETS; NUMERICAL DATA; ORGANIC COMPOUNDS; RADIATION EFFECTS; REACTION KINETICS; SPECTRA