Hydrothermal and magmatic components in the Ruapehu, Pinatubo, Lonquimay and Yasur volcanic ashes

Fresh ash from explosive volcanic eruptions of Ruapehu in New Zealand (1995-1996), Pinatubo in the Philippines (1991), Lonquimay in Chile (1989) and Ysur in Vanuatu (1988) were leached in distilled water in a boiling water bath. The leachates were analysed by ion chromatography and ICP-MS and the chemical composition of leached ash measured by IBA, NAA and XRF. Water-soluble minerals adhering on ash surfaces were examined under SEM-EDX and thin sections of the ash were mineralogically analysed under petrographic microscope. The leachates contain mainly adsorbed material from the volcanic plume and the leached ash insoluble plume precipitates or primary volcanic mineral. At Yasur and Lonquimay, where the erupted material is entirely magmatic, the F/S and F/Cl ratios are 100x to 1000x higher and the S/B ratio 10x lower than in Pinatubo where an extensive hydrothermal system had been extant prior to eruption. In Ruhapehu, the adsorbed material contains a significant component of evaporated Crater Lake water. (author). 9 refs., 1 fig