Published 2011
| Version v1
Journal article
Tris(tetrabutylammonium) tris(nitrato-κ2O,O')tetrakis(thiocyanato-κN)-thorium(IV)
Creators
- 1. Departamento de Fisica Aplicada, Cinvestav- Merida, Merida, Yuc. 97310, (Mexico)
- 2. CEA, Nuclear Energy Division, Radio Chemistry and Processes Department, F- 30207 Bagnols sur Ceze, (France)
- 3. CEA, DSM, IRAMIS, UMR 3299 CEA/CNRS, SIS2M, LCCEf, Bat. 125, F-91191 Gif-sur-Yvette, (France)
Description
The title compound, (C16H36N)3[Th(NCS)4(NO3)3], was obtained from the reaction of Th(NO3)4.5H2O with (Bu4N)(NCS). The Th(IV) atom is in a ten-coordinate environment of irregular geometry, being bound to the N atoms of the four thiocyanate ions and to three bidentate nitrate ions. The average Th-N and Th-O bond lengths are 2.481 (10) and 2.57 (3) Angstroms, respectively. (authors)
Availability note (English)
Available from doi: http://dx.doi.org/10.1107/S1600536811009792Additional details
Identifiers
Publishing Information
- Journal Title
- Acta Crystallographica. Section E
- Journal Volume
- E67
- Journal Issue
- no.4
- Journal Page Range
- p. m487.1-m487.16
- ISSN
- 1600-5368
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- France
- INIS RN
- 45042696
- Subject category
- S36: MATERIALS SCIENCE; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ATOMIC DISPLACEMENTS; BOND LENGTHS; CHEMICAL PREPARATION; CRYSTAL STRUCTURE; NITRATES; THIOCYANATES; THORIUM COMPLEXES
- Descriptors DEC
- ACTINIDE COMPLEXES; ANTITHYROID DRUGS; CARBONIC ACID DERIVATIVES; COMPLEXES; DIMENSIONS; DRUGS; LENGTH; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL RADIATION EFFECTS; RADIATION EFFECTS; SYNTHESIS
Optional Information
- Notes
- 12 refs.