Published October 1981
| Version v1
Journal article
ESR studies of some oxotetrahalo complexes of vanadium(IV) and molybdenum(V)
Creators
Description
ESR spectra of [VOF4]2- and [MoOF4]- have been studied in single crystals of (NH4)2SbF5 and spectra of [MoOCl4]- in single crystals of (NH4)2SbCl5. The spin-Hamiltonian parameters of these pentacoordinated complexes have been obtained and compared with those for the corresponding hexacoordinated species. Molecular orbital parameters for the penta- and hexacoordinated species obtained from experimental g- and A-tensor components have been compared with values calculated by the MS-SCF-Xα method
Additional details
Publishing Information
- Journal Title
- Inorg. Chem.
- Journal Volume
- 20
- Journal Issue
- 10
- Series
- Inorg. Chem.
- Journal Page Range
- 3283-3287
- ISSN
- 0020-1669
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 13663818
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- AMMONIUM FLUORIDES; ANTIMONY FLUORIDES; CRYSTALS; ELECTRON SPIN RESONANCE; EXPERIMENTAL DATA; MOLECULAR ORBITAL METHOD; MOLECULAR STRUCTURE; MOLYBDENUM COMPLEXES; OXYFLUORIDES; VANADIUM COMPLEXES
- Descriptors DEC
- AMMONIUM COMPOUNDS; ANTIMONY COMPOUNDS; COMPLEXES; DATA; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; INFORMATION; MAGNETIC RESONANCE; NUMERICAL DATA; OXYGEN COMPOUNDS; RESONANCE; TRANSITION ELEMENT COMPLEXES